Iridium Oxidation States in Catalytic Hydrogenation Intermediates
نویسندگان
چکیده
منابع مشابه
Iridium Oxidation States in Catalytic Hydrogenation Intermediates
Os conhecidos hidretos de irídio(III) [IrH2(NCMe)3(PiPr3)]BF4, [IrH(h-C3H5)(NCMe)2(PiPr3)] BF4, [IrH(E-CH=CHPh)(NCMe)3(PiPr3)]BF4 e [IrH{C(Ph)=CH2}(NCMe)3(PiPr3)]BF4, derivados do precursor catalítico tipo Crabtree [Ir(cod)(NCMe)(PiPr3)]BF4, foram investigados em reações com substratos tipicamente envolvidos na catálise homogênea de hidrogenação. Novos complexos como as espécies tris-etileno ir...
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ژورنال
عنوان ژورنال: Journal of the Brazilian Chemical Society
سال: 2014
ISSN: 0103-5053
DOI: 10.5935/0103-5053.20140239